Kevin,
You're right in what you post and maybe I should have included all the caveats in my previous post. Yes, water vapor in the atmosphere absorbs and re-emits IR, that's why all the IR telescopes, especially, are on Mauna Kea to be above 95% of the atmosphere's moisture.
I just walked outside with my IR non-contact thermormeter and pointed it at the sky. -74F (-59C) was the reading. It is a clear, cold day, with the sun very low in the sky, NOAA/FAA (at Kenai Airport (ENA to your travel agent, PAEN within Alaska), 3 miles away) reports:
Wind Calm
Visibility 10 mile(s)
Sky conditions clear
Temperature -18.0 F (-27.8 C)
Dew Point -23.1 F (-30.6 C)
Relative Humidity 76%
Pressure (altimeter) 30.55 in. Hg (1034 hPa)
I'm 55 feet above sea level, 80 feet at low tide (big tidal exchanges here).
I noted a 25-30 foot thick inversion layer (based on where the wood smoke settles out) when driving the kids to school, I'd guess that the air at 50 feet is -5F or so. And drier (in absolute humidity) than at ground level.
You're right at ALL matter radiants, but for scientists – those who seek the answer to Life, The Universe and Everything.
And you're right to question if it is a thermally-useful wavelength. As an engineer and especially as a shade-tree stove mechanic, a clear sky doesn't radiate anything of significance to my projects. Whether my sky is -74F or -20C, with that T^4 dependency it isn't a factor compared to 100C pots, 200C gases and 500C stove parts.
Radiation to space (or, as I think of it, the imbalance of radiation up to clear skies versus down to us) IS important for BPers in a lot of realms. It creates cold spots in vallies. It causes dew and frost on tents and plants. It absolutely makes us sleep colder if we're out in the open. And it can drive local weather through katabatic winds.
But you've got me thinking. My simplistic approximation that clear air doesn't radiant significant heat IS true for clear skies in my climate but what about in stove exahust gases which are much hotter AND wetter than any atmospheric air? If there is a bunch of IR bouncing around within a windscreen then you'd want the pot to be black and the windscreen to be bare metal.
So yet again, while the theoretical discussion is very interesting, the answer is really found with a can of black spray paint.