Yep, capillary action is the technical phrase, but i thought it was more practical to give a simple “visual”. I’ve seen some synthetic garments advertised as “wicking”, but didn’t do that, and it’s easy to tell the difference visually.
Bringing air permeability, or the lack of same, into it, probably complicates and confuses the subject a bit as far as wicking in and of itself.
Thank you for the link Matt.
Re: Cap 4 type baselayers, to me, the great benefit of same is not so much “wicking” (it’s not actually that great at wicking, compared to some thin, one layer polyester fabrics), as that it constantly maintains a thin layer of air between your skin and the fabrics over it. That’s about as close to “warm when wet” as you’ll get with a baselayer. As mentioned by others, water is much more conductive than air, and when you wet out a baselayer with sweat or you get wet some other way, the water fills up the spaces between the fibers (which otherwise traps insulating air) and you’re just left with the material that the shirt is made out of to act as a buffer between you and the cold. The conductivity of different common fabric materials range from about .1 to .25 W m-1 K-1. Much higher than air. If you’re wearing a decent insulating layer over the baselayer, you’ll be ok, but your perceived warmth and comfort will go up with a baselayer that maintains a thin layer of insulating air no matter how wet it gets.
Fishnets accomplish similar, and wick very little. In some ways, i prefer fishnets, particularly a polypropylene one. But comfort and aesthetic wise, i prefer Cap 4 type material.
I think highly efficient wicking can be a detriment in extreme cold or cold and wet situations. Because it does speed up evaporative cooling through increased surface area (your skin + the baselayer). One of the reasons why i prefer a fishnet over wicking baselayers for the above conditions, is because it doesn’t do that, but still allows evaporation to occur (in a more natural, slower manner, almost solely from the skin) and again, provides that thin layer of mostly air, rather than wet, conductive fabric.
Like i said, i think all in all, it’s probably more about perceived comfort and warmth, especially if you are wearing layers over the baselayer. But i’ve found, that at least psychologically, it does make a difference. Especially when wind is blowing hard and it’s bitterly cold. Ever wear a wetted out, thin, well wicking polyester baselayer during that? It’s like instant refrigeration or aka “flash freeze”. I find that doesn’t happen as severely with Cap 4, fishnet, or Merino or Alpaca baselayers.
Obviously rate and efficiency of evaporation also depends on the humidity outside of your system, as well as the net air permeability of your system. Wearing a typical WPB system, really slows that down.
Otherwise, and in most conditions, i think wicking is beneficial, especially in heat.


