Hi Dan
Yes, I can make reliable sharp 90 degree bends in 6Al4V alloy sheet (and wire). I use a custom hot bender for this – it's an add-on to my drill-press spot welder. I'll describe how I do it: you may be able to copy. If you succeed, let me know.
Take a short length of 1" brass rod and make a 90 degree notch across one end face, about 3/8" wide at the top. This becomes the lower electrode.
Take a short length of 1/2" brass rod and make a 90 degree wedge at the end. This becomes the upper electrode.
These two electrodes should mate reasonably well, just like an ordinary press bender.
Mount these two electrodes in your spot welder, with the 1" rod at the bottom. How you do this depends on your welder – some engineering may be needed here. Obviously, the two should align/mate properly. You will also need to be able to push the two together with a small amount of force.
Place a strip of Ti across the lower electrode and bring the upper wedge one down on the bend line. Align to suit. Press lightly so the Ti is held in position. Adjust the spot welder so that when you pulse it for maybe 1 second the Ti glows red, and press down at the same time. The Ti will bend beautifully.
While 6Al4V allow will crack if bent too hard when cold, at red heat Ti goes into a super-plastic flow regime, without losing strength. It does not need to be really bright red for this to happen. I think it works OK below spot-welding temperature.

This shows a 6Al4V Ti stove leg with two sharp bends done this way. Quite reproducible.
You may need to fine tune the electrode shapes to get the exact angle you need.
Any questions – fire away.
Cheers