check the forums for clo value comparison for exact numbers. primaloft gold is the warmest synthetic (.92/.9 dry/wet i think), but the nano has gold eco, which is a bit lower (.60s maybe?). fullrange is in the .50s if i remember right.
fullrange has the benefit of more loft and no baffles, so feels a bit warmer as a mid layer. my nano air light (40g fullrange) feels warmer than my nano bivy (60g gold eco), but only under a shell.
face fabrics are very different. nano puff has inner and outer nylon; nano air uses super breathable toray stuff. as an outer layer, the nano air lets more wind through (even with fewer baffles). standing in no wind, air might be a little warmer, even as an outer layer.
i got the nano puff [bivy] on a great sale, but would not buy it again because of how versatile the nano air is. not sure if the sale is still going on, but you can occasionally get the nano air for 50% off.