This coupon had a 1:1 gravimetric ratio of silicone to silica. It is one that used a low-viscosity silicone and higher pressure, and the silicone infiltrated the aerogel particulate. This sample is dense and rubbery.


This coupon was cast on a substrate of nonwoven nylon gauze.

This one was made with a 1:1.6 ratio of silicone to silica aerogel. At this proportion of aerogel, it is crumbly and not robust enough to use without encapsulation that would defeat the purpose of using the silicone binder.

For tent wall insulation, it is hard for me to imagine doing better than down. Even a very clever, meticulously fabricated multilayer IR blanket (Neoair-style), using very thin metallized films (thinner than 12 um space blankets) and very little glue, wouldn’t beat plain old 800-fill down by very much, and it would be much more fragile, more expensive, it would be very crinkly and loud (particularly in wind), and it would render the inside of the shelter pitch black in the daytime. Remember, also, that bare metallized films lose their metal over time when exposed to environmental insults and handling, so the article will have a lifetime decline in R-value, if it doesn’t tear before that curve is observable.
Silicone/silica aerogel composites have been studied, and a literature search turns up a fair bit of research. The military tested it for wetsuits and found it inferior to neoprene for warmth (I think it can be improved), and their numbers show that, by weight, it is a fairly poor insulator. It is only worth investigating for wetsuits because neoprene is compressible (cold at depth) and very sensitive to UV light. Silicone/silica aerogel composites are almost incompressible and almost immune to UV rays. I just mention these studies because there are similar studies about many combinations of fancy materials, and their accessibility (the literature) could save you money.
I think the tent wall application doesn’t really present unique challenges to insulation design. It is essentially the same cohort of design challenges as a sleeping bag. Criteria for weight, moisture management, and thermal properties are about the same for both applications. So, all of the behemoth body of research and discourse on sleeping bag insulation is applicable to your purpose. If an insulation material seems like it would be poorly suited to a sleeping bag, it would probably be poorly suited to an insulated tent, and for the same reasons. At the end of the design process, I think the same material will emerge the winner: down.