I’ve over 40 years of manufacturing, engineering, and R&D in PE. (and more years backpacking)
Yes, the problem for “PE” for backpacking “cooking” is the softening and melting temperature of PE grades used in food baggies.
Melting of PE crystallites occurs through a range of temperatures beginning about 180F and extending above 250F, depending on the distributions of molecular architectures in a given type (grade) of PE.
PE is comprises aliphatic hydrocarbon molecules; it is a synthetic form of paraffin (wax) molecules though having much greater molecule sizes than kids juice drink bottles and Dracula teeth, or grandma’s paraffin put on top of homemade jelly jars.
(Also, one must also consider the scores of chemical additives, comprising hundreds to thousands of ppm typically, that are added to SOME – but not all – grades of PE used for various non-food end use applications.)
Some Grades of PE are specifically, individually approved by the US FDA (and similar foreign) for: Food Contact, Food Cooking, and even Medical Apparatus applications, both temporary bodily contact and permanent implantation.
Returning to the main point for backpacking “cooking”: the issues with using PE baggies are the risk of scalding safety and meal loss resulting from softening and possible gross containment failure (most likely at heat-sealed seams).
If your PE bag does not fail, it’s OK to eat from because it was made from an FDA approved grade of a super-MW-paraffin mixture.
Also, think about what polymer typically makes up the inside, food contacting lamination of the multilayer packaging constructs used for commercial freeze-dried meals. Hint: It is laminated onto the aluminum foil barrier layer to provide an inert, palatable, safe, heat-sealable layer.
Yes, PET and polypropylene grades approved by the FDA for food usage are also OK and will have less risk of gross failure from adding hottest water, since their softening and melting ranges are above those of PE.