Bill: while charcoal is easy to make, and wouldn’t hurt you, what you really want is *activated* charcoal which has been heated in high-temperature steam or nitrogen to drive organics off the surfaces of former cell walls. Then the tremendous surface area of those microscopic structures can adsorb (with a “d” – a surface process) organic molecules from the air or out of water.
If you wanted to use DIY charcoal, the fresher the better.
But you’d have to administer it pretty quickly – before most of the toxics had been absorbing in the GI tract.
So in a pinch, charcoal would be far better to treat the water before drinking than as first aid after you noticed symptoms.