Bob, re:
'So, let me ask the question again. What is the best waterproofing treatment for one Goretex rain shell and one Pertex rain shell?' AND,
'The Pertex wouldn't even last that long and it would be saturated.'
For the GTX shell, the short answer is that there isn't any. To explain: Please note the distinction between waterproof and water repellent. Waterproofing increases the water resistance, not repellence, to a point where water will not penetrate in ordinary use, so is termed waterproof. Water repellence does not do that, but repels water on the surface of the fabric so that is beads up and falls off; thus, preventing water from 'wetting out' the fabric and blocking vapor transmission.
If the GTX rain shell is leaking, the treatment underneath the fabric is no longer waterproof. You could treat the exterior of the garment to be waterproof, but then it would no longer 'breathe,' or allow water vapor to exit, and would be very uncomfortable, unless you are standing around and not exerting, and even then things can get very clammy. So it is probably time to replace the garment. But as Roger suggests, the GTX layer could be failing because it has been contaminated with oils or other substances that destroy the water resistance of the GTX, in which case a couple washings with non detergent soap like Atsko Sportwash might bring it back to life. In that case, it might then be worth it to use a Durable Water Repellent, not resistant, spray on the outer. But after 15 years, I'm betting not.
Pertex also makes waterproof breathable, or WPB materials, but based your report of quick saturation, I'm betting this is not one of them. Even if it were, I've tried one of them on a RAB product and was not impressed. You might be able to waterproof the Pertex using a PU coating product, like McNett TentSure, but it might or might not be compatible with whatever treatment the Pertex received, and again, you would still be left with a non-breathable garment.
So if you want a good WPB rain shell, you'll need to buy one. There are some excellent test articles circa 2011-2012 on BPL on WPB rain shells, and Alan Dixon's earlier article on BPL is very helpful to obtain general knowledge about them. If you email me at scfhome@worldpath.net, I'll send you all the links. My own personal favorite is the Patagonia M-10, around $250 when discounted. The DWR on mine is so good, water doesn't just bead on it, it bounces off and you can't get water to sit on it nohow. But read the articles, make some choices, and find the best deals before warm weather approaches in the US of A and the good sales disappear.