Nylon's moisture regain typically ranges from about 2% to about 9%, with a more specific range of 4%-6% being common. There are different kinds of nylon with different levels of regain.
Generally speaking, while they are somewhat moisture absorptive, they do not absorb a lot of moisture into the material themselves and in most cases can still be considered more or less "hydrophobic", though i would label it more "semi-hydrophobic".
But yes, polyester is significantly more hydrophobic and less moisture absorptive than nylon. However, polyester does absorb a tiny amount of moisture. Only polypropylene or polyethylene could be considered fully and completely hydrophobic–which is also why garments made with them do not need DWR.
Lately, i've been toying with the notion of making a WPB material with a thin, tightly woven polypropylene, sandwiched between two layers of thin, tightly woven nylon fabrics that are treated with silicone ala an EPIC like process. The main problem would be the inner PP material possibly absorbing/accumulating oils. Wearing wool/wool blend baselayers might help a bit with this.
But essentially, it would be a much more durable, beefed up, and potentially more breathable version of Frogg Toggs, Dri Ducks, etc Potentially poor man's eVent or Neoshell.
Now to find a thin, tightly woven, non wicking Polypropylene fabric….