Full disclosure: I own RBTR and created the HyperD line of fabrics.
With that being said, I'll stick to the facts. I haven't tested or seen the "poly D" fabrics (these came out 2-3 months after the HyperD), but I think there are a couple points to make just based on differences between nylon and polyester.
– From just a materials standpoint, nylon is stronger than polyester. Any manufacturer will tell you this and it's one reason industry has gravitated toward nylon over polyester for lightweight fabrics. You can also see it with a basic at home strength test. All things being equal, if you take a strip of poly vs a strip of nylon, say 1.1 oz 20D, it's relatively easy to snap the poly whereas the nylon is very difficult or in my testing impossible to snap with my bare hands. Granted for a UL pack this may be a moot point, but just something to consider.
– All the HyperD fabrics are treated with a DWR for moisture repellency, whereas the PolyD (as stated in specs), has no DWR at all.
– Nylon is naturally resistant to fungi and mildew growth whereas polyester is not.
– Nylon is softer than polyester. Most poly has a fibrous, coarse feel whereas nylon has a more natural, silky feel.