There are lots of choices, from silkweight polyester like Capilene 1 and on up to Capilene 4 and R1, or even 200w fleece if you want to get really crazy— all progressively heavier or course. For really cold weather and sleep, I have a pair of the R1/Dry Power military long johns. REI and Cabela offer Dry Power long johns in lighter weights than the R1. Capilene 2 would be a good middle of the road choice for 3 season use.
You could over-analyze the lighter stuff. For less than frigid weather, any good wicking material will add another layer of warm air next to your skin. I would just go for light cheap and wicking if it's not below freezing. I assume you are in Australia and I wouldn't go for some expensive import unless you really want to split hairs on weight.
I like the light stuff under rain pants rather than wearing typical Supplex nylon hiking pants. That reduces bulk and makes a slippery layer, while keeping the cold fabric off your legs and wicking way moisture.