I just wanted to chime in on my experiences with various bug dopes.
To set the scene, I usually hike in the ADK's. This means lots of wet, swampy areas, rivers & streams, lakes & ponds, hills and mountains. Blackfly's are the bane of most of the NE and Canada. In the ADK's we get between 6-8 weeks where blackflys will coat a red granite rock to literal black. Some trails are low-land trails, like the NPT, most are mixed and some are high-land trails, like the Van Hovenberg Trail.
By far, the most effective bug deterent is heavy clothing and a fine head net. 100% of skin is covered with a layer thick enough or dense enough to stop bites. That said, I never use this. It is just too hot for hiking.
Second best is DEET/Permethrin. While permethrin is not really a repellant, it will kill ticks/mosquitoes/fleas/ants that may get into your sleeping bag and in your cloths. Coupled with high density nylon (DEET does NOT effect nylon) this will limit bites to two or three in a week, even in bug season. However, DEET does NOT work on Deerflies or huge assed horse flies. In some areas, they can still swarm you.
Third best (still with permethrin on my clothing,) Picarden works slightly better on mosquitoes, but not at all on blackflies (except for about 5-10 minutes after being freshly applied.) But, it only lasts about 30minutes to 1.5 hours. For comparison, DEET will last untill it is washed off or sweated off. I will use DEET knowing 4-5 applications in a week will be enough. With Picardin, I use a bottle per day. I got about 20 bites in a 4 day period.
Lavender Oil doesn't work in the ADK's except for a few mintutes of being freshly applied. Citronella doesn't work. I used three bracelets of citronella, my right arm got 12 bites. My left arm (DEET) got none. Over a three day period, I decided that was enough. Skin-so-soft doesn't work in the ADK's. Mosquitoes will still bite right through it. I believe the oils may deter the mosquitoes as much as the item being used, but this is a quess, only. Eucalyptus Oil works slightly better than citronella. It is not worth carrying to me. Pepermint, cedar, lemongrass all work as well as eucalyptus with varios effective times between 10 minutes and 30 minutes. An old time "bug dope" was kerosene and light tars. It was more effective than lemongrass. (I used it fishing the Black River in Forestport as a kid.) I remember getting about 1 or 2 bites per hour (and needing a bath when I got back…)
The risk of infection and disease is higher than the risk from DEET and permethrin. Permethrin should not be applied to skin or undercloths.