Max, UHMWPE equals dyneema, spectra, or the cheaper, lesser quality generic versions from China etc. It's a form of Polyethylene plastic. The PE part on the end stands for polyethylene, the rest is ultra high molecular weight. Polyethylene in general has some very similar, and yet very different properties than Polypropylene. They are both extremely hydrophobic and very light weight materials. This is why Dri Ducks, Frogg Toggs, O2, etc. polypropylene based rain wear doesn't require a DWR coating–the high innate hydrophobic level of the material. But because these are non woven forms of polypropylene, they tend to be fragile. Woven forms of polypropylene tend to be significantly stronger and more durable though–but i've yet to see rain wear using woven forms.
The main difference between ultra high molecular weight polyethylene and polypropylene besides the massive difference in strength/durability, is that UHMW polyethylene is extremely heat conductive in nature and P.P. is extremely thermally non conductive. This makes the former lend itself well to warmer weather activities and the latter to cold weather activities.
Regarding number 2. Under heavy and long enough rain the outer fabric of most every kind of WPB rain jacket will eventually wet out and get soaked with water. But the membranes will still prevent water ingress through to the skin, but meanwhile if you're active and it's a bit warmer than "cold", you will wet it out via sweat because the breathablity of a soaked fabric plus membrane equal pretty poor.
At least with a soaked houdini or the like, and a more breathable midlayer (in this case polypropylene), the breathablity still remains fairly high.
Regarding number 3. Apparently you missed my question at the end? I was asking if others had already experimented with a similar set up, and if so, what was their experience. If a bunch of other people have already tried it and found it didn't work, then probably no point in wasting time in even trying it to begin with–hence i'm interested in more than just theory. Oh, i like theorizing, but at the end of the day i'm also deeply practical and more experiential based.
The fact that i haven't seen anyone here talk about using a similar set up though, inclines to me believe that it probably hasn't been tried a lot, hence the specific question directed to all of BPL.
Re: 4. Yah, i agree, when it's warm enough out, that's what i do, just get wet–especially when it's 70+ out. However, there's that range of temps with rainy conditions from about 45 to 65 or so for the high of daytime, which depending on the type of rain involved, can be tricky even if you're active. Especially if it's a cold rain. You can get hypothermic even at those temps. Even if it's 65 high for daytime temp, in the mountains, it can quickly drop a lot more when it starts to get dark. But that temp range i find is too warm for most WPB systems that i've tried.
Neoshell looks interesting, but it tends to be pretty expensive and there is a growing concern about the long term durability of these kind of membranes. I also like the idea of using a umbrella with a partially opened windjacket (or half poncho), but there are times when i like my hands free too. Some have rigged up an attachment system to their packs, but since i regularly cycle between 3 different packs, i would have to rig up three different systems. Conventional ponchos are ok, but still find them a bit over warm at that specific range. Would love to try the eVent packa, but it's pretty expensive and fairly heavy.
I just don't think we have reached the pinnacle of WPB rain gear systems, which is why i like trying to explore alternatives to same. I have high hopes for UHMW polyethlene eventually being used as an outer material, and maybe also as a mid layer next to outer layer for WPB systems, but if a company goes with Dyneema or Spectra brand it will be really expensive (more because these are "brand names", than actual cost of the material itself). If someone used a generic no name brand of UHMW polyethylene fiber in combo with polypropylene fiber to construct such garments, should be fairly reasonably priced. Meanwhile, polypropylene though not ideal like UHMWPE, in the woven (and stronger and more durable) forms still has a lot of potential i think for cheaper WPB systems.