Way back in June I posted –
… per Mr. Nisley, 2/18/2010
"A DWR works by creating a low attraction (surface energy) between water drops and the fabric. This allows the water drop to roll off rather than flatten out and stick to the surface.
"The fluorochemical DWR molecules on the outer surface of your eVENT jacket contain a vinyl or acrylic polymer that sticks to the fabric. Attached to this backbone are little perfluoro tails (side chains) that are normally repelled from fabric surface by polar forces and stick up into the air. The little tails are what creates the low surface attraction to the water molecules and keeps the DWR working. Sustained exposure to water or abrasion will cause the tails to flatten out and the DWR to stop working. Heat of at least 140F is needed for about 15 minutes to create enough molecular motion for all of the tails to fully stand back up again. [ Throw it the dryer for 15 minutes and remove immediately. gm]
"… For others using Nikwax or a Silicone DWR, heat will provide no benefit. In order of durability the above DWR type is the most durable, silicone is next, and wax is last."
So I wouldn't mix-and-match fluoro's with wax or silicone.
By "covering" a fluoro with wax you are essentially re-engineering the DWR and committing to wax for the remaining life time of the garment.