"Propane is a slightly smaller molecule than butane, so it tends to concentrate slightly near the bottom.
Really? At the bottom of what? I rather think the thermal energy of the molecules will ensure a pretty even distribution in something a small as a canister on planet earth."
Yeah, very small, ignore it.
"Take a cold canister, put it in some warm water and listen – you WILL hear it fizzing inside."
Yeah, that can happen. But this doesn't effect the over-all steady state pressure as you use the stove, well slightly decreasing. You just need to calculate at the new temperature. In your example, once it hits around 32F/0C it should stabilize again, within a minute or two, I would guess. Boiling is simply the explosive release of vapor pressure. In a closed system, this cannot happen, except as you say, by greatly changing temperature/pressure conditions. The valves(lindal and control valve) *limit* the flow of gas and/or liquid. There needs to be positive pressure in the canister for the stoves to work. The pressire also acts on the liquified gas varying the vapor pressure AT the boiling point of the new system. Not above it or below it. (Actually as you burn the gas it is slightly decreasing, drawing more gas out of the liquid state, but not really boiling, vapor pressure is usually enough.) Like boiling water in a closed vessel. Unless you actually flash heat it, no boiling happens till it actually explodes, then ALL the superheated water (at the new lower pressure) will try to boil till it reaches a steady state again.
The data was from: http://www.engineeringtoolbox.com/propane-vapor-pressure-d_1020.html
Your right, I just realized the tables were not all in bars, the F temps are in PSI. Sorry about my mistake. Looks like -13F/-25C will supply about 2 bars. Again, my apologies. I will correct it in the above note.
Anyway, from this it is possible to conclude that the interior surface of the LP gas inside a canister may be more important than we previously guessed. The concave bottoms, once exposed inside, probably cause lower volumes of gas to be available for use…perhaps the last sixth or so of the canister.







