Regarding shelter fabric selections, there are a couple of issues worth noting about silnylon.
The first is that standard silnylon does not satisfy the fire retardancy laws in several jurisdictions including MA, NY, NJ, LA, MI, MN, CA and Canada. That's why larger manufacturers and retailers (like REI) won't ship silnylon shelter products to these places.
Small companies, however (like Tarptent, Six Moon Designs, Oware, etc), seem willing to take more risk with these laws, probably operating under the theory that silnylon products are intended for advanced backpackers who understand the fire risks. However, the first time that someone is seriously burned in a silnylon shelter and brings a lawsuit against a manufacturer, I'm guessing this could all change.
Many lightweight shelters sold by larger companies now use a combo silicone/polyurethane coating on tent fabrics that does satisfy the fire retardancy laws. This double coating, although heavier, also allows the seams to be taped and makes the fabric somewhat more waterproof, helping to mostly solve problem #2 (below).
The second issue is that if the silicone impregnation is applied too lightly, rain will eventually find its way through the fabric, usually in the form of a fine mist. If the rain comes down hard and long enough, this mist can add a non-trivial amount of moisture to the interior of the shelter. I've designed and built several silnylon shelters and can verify from experience that this is true.
On a good day, standard silnylon is only waterproof to 1-2 PSI. However, as the fabric ages with stretching and UV exposure, it can become even less water resistant.
I've never owned a Golite shelter, so I haven't had a chance to examine the fabric myself. Their website, however, makes no mention of PU coatings on SilLite, so I'd guess that the additional fabric weight is probably the result of heavier silicone impregnation and/or the addition of a fire retardancy agent.