I just bring one extra pair of socks, 1-2 pairs thin liner gloves, and 1 pair warm gloves for sitting around camp or emergency. I also usually have a light fleece beanie and a really warm hat. Also, an insulating jacket/parka and maybe insulated pants.
Synthetics are generally colder than wool when wet, but dry quickly. Wool dries more slowly, but is warmer than synthetics when wet. This means that in general, wool is a good option for things like socks and pants which are likely to remain wet for a long time, and synthetics are a good option for things which are easier to dry or more critical to remain dry. Thin layers of merino wool dry pretty fast though. I like wool socks and a little merino wool blended with polyester base layer pants. (Although, I intend to try synthetic soft shell pants this winter.) I often hike in a light fleece hat, and it's soaked with sweat before I even realize it. A merino wool hat lets me know that it's soaked with a slightly cold, clammy feel. With the fleece hat, a few slaps of it against a pants leg makes it feel dry again, not so with the merino wool hat.
Edit 1: Regarding fire, I don't carry anything more than a 4" Mora fixed blade knife (3.2 oz) which I baton to split wood 3" diameter or less. This is usually sufficient for a 2-3 hour fire in less-traveled areas.
Edit 2: I also look forward to trying out a new canister gas stove this winter. It'll be nice to have a hot meal and not have to work for a campfire or fiddle with an alcohol stove. It'll also be critical to keep the canister warm though.