My ONLY experience with Primaloft was 10 years ago with my Caribou Mountaineering summer bag. It lost over 1/2 its loft in 2 summers. Since then I have avoided Primaloft. That said, the new Primalot versions have likely improved its loft retention. Good storage is the key to retaining loft in synthetic insulations.
My experience with Thermolite Micro specifically (they have other versions too) has been very good. I've used my Thermolite Micro jacket and pants insulating layers in late fall and winter backpacking trips. It stuffs down very small and regains loft well, over and over.
As an addition to my 30 F. WM Megalite bag the suit has helped me sleep comfortably into the teens F. On Pennsylvania deer hunting tree stands the Thermolite Micro jacket and pants have kept me cozy under GTX parka and pants for long hours of freezing temps.
As you can see, I'd recommend Thermolite Micro as a good synthetic insulator.
BTW,
Climashield may be as good or better. WHAT WE DESPERATELY NEED IS OBJECTIVE TESTING FOR THEMAL EFFICIENCY AND LOFT RETENTION OF SYNTHETIC GARMENT INSULATION.
(BPL, are you listening??)