I have used the first generation Lithium with Pertex Quantum inside an Equinox ultralight bivy in similar temperatures (northeast) for up to 3 nights. I use a full length closed cell pad under the bivy with a 3/4 length inflated pad inside, as my Exped Downmat has sprung 3 consecutive leaks and goes flat overnight.
Regardless, the silnylon bottom of the bivy usually has some frost, and there is occasionally some on the underside of the bivy top fabric, but as has been mentioned, this is easily shaken off. For trips of up to four days, I have never had problems with frozen moisture inside the bag- so long as I take care of my feet and breathe.
Your exhalation can cause a good deal of ice buildup around the face opening of the bag- so this is where you want to bivy to protect form internal moisture. Nylon is fine, it is more important to have good coverage around the opening.
Also, I have experienced ice buildup in the footbox- bivy or no. Using plastic bags over liner socks and under down booties or heavyweight socks eliminates this.
With these provisions, I have had good experiences with a plain nylon top bivy in conjunction with various taprs in the Catskills and Adriondacks.