I have experimented with solar power while backpacking extensively. I own 3 chargers including a lightweight homebrew model. It works well if:
1) The sky is sunny AND…
2) There is an absence of tree cover/deep canyons or anything else that blocks the sun AND…
3) The panel is properly oriented toward the sun.
In my experience on the JMT, HST and TRT these 3 conditions did not exist often enough to justify the weight and bulk of the charger. I came to the conclusion that simply carrying extra cells was lighter and simpler and cheaper. Of course that was just my personal experience and YMMV under different conditions.
One specific example: I was on the TRT (Tahoe Rim Trail) for a week at the time of the Summer Solstice. My goal was to charge 2 NiMh 800mA AAA cells at a rate equal to the power consumption of my Garmin Foretrex 101, switched on for 6-8 hours per day. I used a homemade solar array with an output of 100mA and 3.6 volts. Physically my panel was about 18 square inches (3"x6") and the weight was 1.1 ounces. I carried two sets of AAA's, one in the charger and one in the GPS.
In addition, I carried a Solio 3 leafed charger. I planned to use that to recharge my Ipod 30gig classic which I used for about 3 hrs of music and maybe an hour of video every day.
I had both chargers on my pack all day long and I set them up in camp to catch more sun in the evening. When I went to bed I oriented the panels to the east to catch the next day's rising sun. This was during the longest days of the year. My charger also had a diode to prevent the loss of current back to the panel at night.
In my case neither charger came close to keeping up with demand. After an entire (solstice) day of exposure my 2xAAA charger was only able to move the cells up one bar on the GPS's state of charge display. The Solio fared no better with my Ipod.
The problem was, even with a sunny sky I had to fight a constant battle to keep the panels properly oriented. The top of my pack had barely enough surface area for the two chargers. My head and hat constantly shaded them. Some days were cloudy. Some days were spent mostly under tree cover. They worked well if I placed them on the front of my pack (as in the pic above) AND the sun was at my back AND I wasn't under tree cover but that was rare.
Keep in mind that the rated output from any solar charger is a maximum under ideal conditions. In the real world it will be less and sometimes much less. Those recharge times claimed by the manufacturers are under perfect conditions. And when you check the weight of a charger factor in a set of cells as well.
I haven't given up on solar power for backpacking but it does have severe limitations. If it's ever going to work for me on another thruhike I'll have to lower my consumption, increase my output and generally lower my expectations. If one were to base camp in a sunny spot without excessive power demands it would be ideal. On a long trip without the possibility of resupply it would also be ideal. I'm considering the idea of doubling the output of my AAA charger to 200mA but that will require 36 square inches and that's a lot of real estate on my pack. Even at 18 square inches it compromised easy access to part of my pack.
If you have the ability to keep a fairly large panel in the sun for most of the day and your power needs are not too high, solar power may be for you. Hopefully thin cell solar panels will become much more efficient in the future.