I've sealed the floor of my bivy made of silnylon, both inside and outside
It wasn't completely waterproof before
I used generic silicone caulk diluted with "odorless" mineral spirits, 1 part silicone to 3 parts spirits, by weight
outside (surface that contacts ground) didn't work very well, after about 10 nights it started peeling off. I finally "helped it" and got most of it off. The flakes of sealant were a bit of a mess.
inside (surface that contacts my sleeping pad) is good after maybe 100 nights. much more waterproof than before I sealed it
I've used McNett seam grip on PU coatings a number of times. YOU HAVE TO REMEMBER TO COAT WITH POWDER AFTER IT DRIES TO PREVENT STICKING AGAINST ITSELF!!! I keep forgeting this and it makes a complete mess when you do this :) I scrape off some Gypsum board like used for walls in houses which doesn't smell. Silicone doesn't have this problem.
That stuff works very well (on PU). I repaired a pack where a mouse had chewed a hole and it worked really well.