My silicone spray tip was a tip I got from a gear manufacturer in a phone call back in ’99. McNett does sell a silicone spray for water resistance on some materials (as well as many other treatments) – http://www.seattlefabrics.com/mcnett.htm – so I know the treatment has been around for a while.
All applied treatments are active ingredient(s) suspended in a solvent. The solvent and active ingredients need to be compatible with the composition of the fabric it is applied to. The wrong refresher can degrade the original coating. Fabrics like Epic do not have a DWR coating so they do not need recoating. Another issue is whether or not the new coating will adhere. The wrong coating could just rub off because it will not chemically or physically bond. So this is a chemistry issue.
For example, the Golite Helios mentioned in the original post is DWR-treated ripstop nylon with an acrylic coat. Sounds like the DWR is applied and can wear off over time. An acrylic compatible refresher coating is indicated in this case. Check the ingredients of the recommended DWR refresher for the fabric to see if a cheaper substitution can be done.
When making gear, I consider minutia like this when I choose the best material with the properties I want. I don’t try to “improve” the fabric – only design, construction, and upfront cost.
My silicone tip came from Stephenson Warmlite – http://www.warmlite.com/start.htm. That company seems to be a bit radical at first glance. But I notice that the tent they have designed and sold for many years have some very similar design features as Henry Shire’s new line of TarpTents. So they do have some good ideas.